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ILLUMINATI PSYCHE TWO STATION 2 -STORY SCROLL SITE
-AND-
-WEBSITE CONGLOMERATION PATH REPORTING--
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DISCLAIMER--
IDEAS ISSUES IF
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PATH ELECTRIC AND ELECRTROMAGNET STORY ROUTE WITH PATH STORIES OF ROUTE NOTES
COPPER IN PATH OF NUCLEAR GAS STORIES ROUTE NOTES
PATH ELECTRIC 2 DIRECTION UNDERWATER ROUTE STORIES NOTES
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FOREVER ABSTRACT ISSUE TO FOOD TO SPACE TO BACKWARDS STORIES ROUTE WITH LIFE ISSUE TO FOREVER STORIES NOTES
PATH WITH STEM CELLS AND CELLS STORY ROUTE WITH TOPIC OF MUTATIONAL STEM CELLS NUCLEAR NANO AND BRIDGE SALT STAGNENT STEM CELLS TOPICS WITH LIFE STORIES OF ICE STORIES TOPICS OF PASSAGE ROUTE NOTES STORIES OF DREAMS OF FROZEN IN GREEN VAPOR STORIES
THIS STOYR OF PATH TOPIC OF GREEN VAPOR TO ROUTE ICE STORIES OF EFFECT MEMORY ROUTE WITH LIFE STORIES
TOPIC IN MAX TRANSPORTATION STORIES NOTES PATH NOTES
TO STORIES OF ROUTE WORKING CONCUBIND STORIES OF DOT ICE ALSO ROUTE WITH STORIES
AND THAT STORY OF TOPIC ROUTE WITH STORY OF ROUTE GREEN VAPOR STORY IN ROUTE OF ISSUE PATH NUCLEAR GAS STORY PATH WITH TOPICS ROUTE WITH WORK WITH STORIES OF EFFECT WEATHER STORIES ROUTE WITH PATH
IN HISTORY WORKED TAR WOOD STORIES ALSO
AND THE STORY OF TOPIC OF SMOKE NUCLEAR GAS WAS IN STORIES HISTORY ROUTE OF REJUVINATE BATTERY STORIES NOTES
TO THEN MAKE ELECTRIC NOTES STORIES NOTES
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TO GREEN VAPOR STORIES NOTES PATH WITH NOTES
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TOPICS OF EFFECTED BY STORIES OF TOPIC ELECTRIC 2 DIFFERENT DIRECTIONS STORY UNDERWATER TO REACH STORIES OF PATH ROUTE OF CYROGENIC STORY OF PATH WITH VINEGAR BAKING SODA OF METHODIC EVENT OF BALL SPRING PRESSURE CANNISTER STORY ROUTE WITH PATH STORIES OF ISSUE TOPIC OF PATH VORTEX CANNON ROUTE OF PATH WORK ROUTE OF TUBE IN AND TUBE OUT STORIES OF CANNISTER ROUTE OF STORY TOPIC
ALSO NOTE STORIES OF ROUTE TOPICS OF TUBE OUT RIGHT AWAY STORY IN TIME NOTES WORK 2 DIRECTIONS
IN BACKWARDS STORY ROUTE WITH GREEN VX GAS IN THIS ROUTE PREFIX SUFFIX ISSUE STORIES NOTES OF DROPPING DOWN OUT OF CANNISTER RIGHT AWAY NOTES
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PATH EFFECT WEATHER AND EARTHQUAKES ROUTE STORIES NOTES
PATH OF ROUTE USE THE HISTORY OF COPPER 27 DOUBLE LEVERAGE ROUTE OF STORY ISSUE PATH OF BATTERY AND ELECTRIC
INTO 2 DIRECTIONS UNDERWATER ROUTE STORIES PATH WITH TOPICS
TO STORIES
SIDE NOTE IN PATH OF STORIES OF ISSUE TOPICS OF NOTES
CANNISTER TOPICS WITH VX GAS VORTEX CANNISTER PATH WITH NOTES PREFIX SUFFIX ISSUE NOTES
TO STORY OF 2 DIRECTION UNDERWATER ROUTE TO CYROGENIC CHAMBER STORY TOPIC
WITH ELECTRIC ELECTROMAGNET
ELECTRON PROTON BASHING DOUBLE
AND PATH WITH TELSA COIL ROUTE WITH STORIES
IN COIL AND 27 COPPER COIL ROUTE TOPICS OF COIL ELECTRIC ELECTRO MAGNET PATH WITH STORIES
TO WONDERS ADD STORY OF COPPER ELECTRO ELECTRO MAGNET
OF BATTERY STORY UNDERWATER TOPIC OF THAT STORY ISSUE
ROUTE OF 2 DIRECTION STORY ROUTE WITH PERHAPS A STORY
OF NOT AN ELECTRIC STORY GET INTO THE TERM COMPLETE IN LIFE ATTITUDE WITH THIS PATH OF ROUTE STORIES
IN TOPIC
ADDING ELECTRIC ELECTROMAGNET TO COPPER COIL
AND ISSUE IN ROUTE OF TELSA COIL AREA AND TIN DISSOLVE AND ROUTE WITH PATH ELECTRON PROTON BASHING ROUTE
STORIES OF ELEMENTS IN THIS PATH OF STORIES
IN TOPICS OF DOT AND SPHERE STORIES ROUTE NOTES
PATH NOTES
DOT BASHING STORY ELECTRON PROTON
AND TELSA COIL STORY OF SPHERE STORIES ROUTE WITH STORIES OF PATH NOTES ELECTRIC ELECTROMAGNET NOTES
IN POWER ANCHOR STORIES COMPLETE STORIES BEGIN TO WORK
SO THE STORY OF TOPIC OF ISSUE GREEN VAPOR STORY
IN NUCLEAR GAS WORK THIS STORY ROUTE WITH NOTES
TO STORIES OF WHY BATTERY UNDERWATER TOPIC IN POWER ANCHOR STORIES NOTES
AND COMPLETE IN STORIES ADDING ELECTRIC ELECTROMAGNET TO COPPER ROUTE
WAS A HISTORY OF MURITIC ACID 6 MOTIONS STORY
NOW IN 6 HEIGHT GAS PATH TO USE THAT STORY IN ROUTE WORKING WITH POWER NUCLEAR ROUTE WITH SMOKE PRESSURE
SPIN STORIES NOTES
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ISSUE TO NOTES PATH OF TOPIC OF STORY OF DOUBLE LEVERAGE COIL COPPER ROUTE WITH STORIES OF TOPICS OF ISSUE TO STORIES OF NOTES THE VARIATION OF THAT AND A COIL ROUTE WITH PATH ELECTRIC AND ELECTROMAGNET PATH STORIES OF EFFECTED BY THE ROUTE OF 2 DIRECTIONAL BATTERY UNDERWATER ROUTE WITH TOPIC OF EFFECT TIN DISSOLVE UNDERWATER ROUTE PATH WITH STORIES OF ROUTE THROUGH THAT PATH ROUTE STORIES INTO A CHAMBER OF ISSUE STORIES OF PRESSURE TO NOTE STORIES OF CYROGENIC STORY OF COLD EFFECT METHODIC EFFECTED STORY OF BALL SPRING TO BUBBLES ROUTE STORIES TO BOTH COLD MATTER VARIABLES AND METHODIC STORY ROUTE TO CYROGENIC STORY NOTES TO TOPIC OF BATTERY VARIANCE ELECTRIC ISSUE STORY ROUTE WITH DOUBLE LEVERAGE COPPER ROUTE STORIES OF TOPIC PLANE TO COIL ROUTE EFFECTED IN 27 COPPER COILS TOPIC ROUTE OF PATH NUCLEAR VAPOR STORIES THAT ONCE WORKED STORY OF ROUTE NOTES TOPIC OF SHAKE ISSUE GREEN NUCLEAR X PREFIX SUFFIX ISSUE DRAW TO STORY OF ROUTE TOPIC OF ISSUE STORIES NOTES OF TURBINE DISK SPIN GAP TUBE STORIES NOTES TOPICS
SO THE STORY OF 6 HEIGHT GAS ROUTE TOPIC REACHED THE STORY OF PATH WAS A HISTORY OF COPPER COIL DOUBLE LEVERAGE STORY OF TOPIC OF ISSUE STORY OF ISSUE BATTERY VARIANCE ELECTRIC STORY TOPIC OF BOTHERS TOPIC OF LIFE IN MURITIC ACID 6 MOTIONS STORY IN LIFE 3 BACKWARDS AND 3 FORWARD STORIES NOTES TOPICS NOTES
WHICH WAS ONCE THE STORY OF ROUTE TOPICS OF PATH STORIES NOTES 6 MURITIC ACID MOTIONS
NOW IN 6 HEIGHT GAS HISTORY ROUTE LEMON AND LIME NOTES
THAT STORY OF TOPIC ROUTE STORIES WENT TO STORIES OF PATH NOTES
ISSUE TO PATH
THE STORY OF GREEN VAPOR ROUTE WENT TO STORIES LIGHTENING TURNED GREEN NOTES EVENT PATH OF WORKING WITH 2 DIRECTION OF ELECTRICITY UNDERWATER PATH TO BEGIN WITH NOTES
OF TOPIC OF NOTES HYDROGEN SULFIDE METAL TOPICS NOTES PATH INTO BRIDGE SALT STORIES ROUTE TO TOPIC OF STORIES PERHAPS THE STORY OF ICE STORY ROUTE WITH CLONES REACHED A STORY OF LIFE WITH TOPIC OF STORIES OF LIFE WITH CONCUBIND STORY ROUTE WITH LIFE NOTES AND PERHAPS THE TERM COMPLETE IN LIFE STORIES ROUTE WITH TOPICS BEGIN STORIES NOTES
THE ROOM OF THE PATH OF STORIES OF TOPIC OF 6 HEIGHT GAS STORIES OF LEMON AND LIME PATH TOPICS OF PRESSURE NOTES STORIES
SO THE PATH OF GAS REACHED LEVELS OF LEMON TO ALCOHOL BEFORE SALT
AND PATH WITH STORIES OF TOPICS ROUTE I PREFIX SUFFIX ISSUE HEIGHT TWICE STORY ROUTE WITH GREEN MATCHES STORY
ROUTE WITH TOPICS TO ACETONE ROUTE WITH STORIES TO PATH OF ROUTE WITH NOTES LIME MOLD ROUTE WITH STORIES
PATH NOTES IN STORIES OF METHYL ALCOHOL ROUTE WITH STORIES OF PATH WITH NOTES ISSUE STORY TO NOTES TOPIC
STORIES ROUTE WITH NOTES PATH NOTES BLUE LUBE AND RED LUBE STORIES NOTES TOPICS PATH NOTES
THE STORY OF FORMALDEHYDE WENT TO STORIES OF PATH LYE FLOWERS 5 TO 6 STORY ROUTE OF
PATH DANDELION AND SUNFLOWER AND PATH WITH NOTES WHITE AND PURPLE FLOWERS AND PATH WITH CHAMOMILE STORY ROUTE WITH NOTES
AND PATH WITH NOTES LAVENDER ROUTE TOPICS WONDERS PERHAPS
THE VARAIBLES OF LYE TO FLOWERS TO WORK STORY OF PRESSURE
NAMES OF THE FLOWERS TOPIC TO ACTUALLY THAT PRESSURE OF THE FLOWERS TO WORK WITH TOPICS
ROUTE WITH STORIES
TO STORIES WORKED THE TOPIC OF UV ROUTE PREFIX SUFFIX ISSUES WITH STORIES CHAMOMILE ROUTE WITH FORMALDEHYDE 27 1 SALT PATH ROUTE
TO STORIES OF TOPIC NOTES ISSUE ROUTE WITH NOTES UV PREFIX SUFFIX ISSUES AND WHITE ROUTE WORK UV ISSUE STORY ROUTE WITH TOPICS
OF PATH WITH LIFE STORIES OF ISSUE TO NOTES THIS PASSAGE SKIPPING THE SUNFLOWER BOUND TO THE FORMALDEHYDE AND
PATH WITH NOTES STORIES WITH THE ROUTE OF THE TOPIC OF BOUND AGAIN IN TOPIC
WONDERS
IN WORKING PURITY WITH UV STORIES ROUTE WITH AND WORKING STORY OF ANHYDROUS AMMONIA ROUTE WITH PATH NOTES
POTATO WHITE GLUE VINEGAR AND AMMONIA AND GOO AMMONIA TOPIC ROUTE WITH STORIES WONDERS
NOTE LYSOL PRODUCT NOTES TO PATH WORK POWER ROUTE STORIES TOPICS ROUTE WITH TOPICS OF LYE MURITIC ACID TO STORIES
OF POTATO AND DIRT AND SALT STORIES TOPIC TO ADD DIRT TO THIS PATH WITH STORIES NOTES
AND WORK WITH ANCHOR ROUTE WITH TOPICS OF LIFE WITH DIRT VARIABLES OF TOPICS WITH POWER STORIES AND THAT WORK WITH PATH OF ROUTE STORIES NOTES ISSUE TO NOTES PATH NOTES TO ANCHOR POWER AND ANCHOR ISSUE OF PATH ROUTE NOTES ISSUE TO ANHDYDROUS AMMONIA EFFECT PATH WITH STORIES OF CHOOSE A STORY NOTES
TO THE TOPIC OF ROUTE ISSUE
WORK WITH ANCHOR STORIES TO POWER ROUTE WITH TOPICS BEGIN ROUTE WITH NOTES STORIES NOTES
TO STORY OF THAT ROOM TO WORK STORIES OF TUBE RISE STORY WITH PATH LIGHTENING PRESSURE MACHINE AND EARTHQUAKES NOTES
IN TOPIC OF THAT TUBE ROUTE WITH STORIES OF TRIANGLE AND CUBE STORIES OF PATH WITH LIGHTENING STORY LINK WITH ROUTE IN STORIES
OF TOPICS OF 3 COIL TO TUBE ROUTE WITH STORIES OF PATH TRIPLE DENSE AND TRIPLE MOTOIN STORY NOTES
AND PATH WITH STORIES OF ROUTE WITH TURBINE DISK SPIN STORIES ALSO NOTES
TO WORK A STORY OF ROUTE NOTES
THIS MACHINE WORK WITH UNDERGROUND TOPICS NOTES
IN VARIANCE TO UNDERWATER STORIES ROOM TO PATH TOPIC STORIES
TO PATH WITH GIANT BODY TOPICS ROUTE WITH STORIES OF ROUTE TOPICS ISSUE TO NOTES STORIES
OF PATH NOTES
OF RESEARCH PROJECT ROUTE WITH LIFE STORIES OF TOPIC OF ISSUE ROUTE
WITH A 4 STORY OF GOAL CHANGE GOAL AND WORKER AND CHOOSE WORKER ISSUE STORY
WITH DOUBLE BLACK AND WHITE STORIES OF THAT VARIABLE NOTES
TO STORY OF ROUTE WITH NOTES STORIES OF ISSUE
THAT STORY ROUTE WITH TOPIC THE PRESSURE OF GIANT BODY STORIES ISSUE NOTES
TO THE VARIABLE OF HOUSING STORY OF SILICONE NITROGEN METAL
TO VARIABLES
OF STORY HYDROGEN SULFIDE AND PATH WITH LIGHTENING
AND PATH WITH NOTES
TO STORY OF TOPIC OF 5 ANTENNA STORY OF ISSUE ROUTE WITH PROPYELENE GLYCOL OF PRESSURE TOPIC
OUTLINE SIDES WORK WITIH SPIN ELECTRIC TWICE IN CUBE STORY TOPIC ISSUE ROUTE
TO STORIES OF ISSUE JUST DO ONCE WITH ISSUE IN ROUTE SPIN COPPER MAGNET STORIES NOTES
ELECTRIC TOPIC IN CUBE IN STORIES
OF WHAT IS THE DIFFERENCE IN CUBE PRESSURE TO THAT STORY
ROUTE WITH STORIES OF LIFE WITH NOTES CUBE STORY OF TOBACCO ROUTE OF OUTLINE SIDES STORY OF TOBACCO
AND PUT POLE IN MIDDLE LEVERAGE ISSUE TO VARIANCE OF ISSUE TO JUST CONNECT STORIES
THESE TOPICS IN LIFE REACH STOREIS IN LIFE ISSUE TO WOMEN IN LIFE STORIES ROUTE WITH LIFE NOTES ISSUE
TOPICS WITH LIFE NOTES PATH WITH T BAR STORIES ROUTE OF HALF TUBE UNDERGROUND AND HALF ABOVE GROUND STORIES
VARIANCE T BAR STORIES WORK WITH STORIES OF 2 T BAR ROUTE CONNECT TO EACH OTHER STORY OF TOPIC PREFIX SUFFIX ISSUE
OF STORY ROUTE WITH NOTES THAT TOPIC IN DOUBLE LEVERAGE NOTE STORIES NOTES PATH WITH STORIES
OF PERHAPS TUBE UNDERWATER BRIDGE ON STORY WORK WITH T BAR ISSUE PREFIX SUFFIX ISSUES STORY
OF PATH WITH
STORIES NOTES ALSO REACHES STORY OF PRESSURE WOMEN IN LIFE TO STRUCTURE WORK WITH MOVIES STORY PERHAPS A STORY
OF GET OUT OF STORY IN LIFE WONDERS ISSUE TO STORIES GET BACK INTO STORIES OF LIFE WITH NOTES
TOPICS WITH LIFE STORIES OF MAKING STUFF NOTES
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PERHAPS TO WORK
THE STORY OF ROUTE ISSUE TO TOPIC
OF TARGET LIGHTENING WITH CUBE VARIABLES UNDERGROUND TO TRIANGLE STORIES ROUTE WITH STORIES
TO HAVE TO WORK THAT ROUTE TRIANGLE TO CUBE CONSTANT STORIES DOES NOT SEPERATE 2 ISSUE STORY
TO STAY WITH
FLURRY AND FUZZY ROUTE WITH TOPICS OF OPIATE ROUTE WITH STORIES OF ISSUE ROUTE ONE ROUND OF ATTACK
EXTRA PLANE 911 STORY ROUTE WITH TOPICS
OF WORKING DIGNITY AND EGO STORIES OF LIFE ISSUE STORIES NOTES
TO TOPIC OF ISSUE TO THE EFFECT OF IMPLICATION OF ISSUE STORY TO BE A VARIABLE IN LIFE OF UNDERWATER TO TUBE TO BRIDGE
STORY ROUTE WITH PATH DOUBLE GRAVITY VALUE PLANET AND PATH WITH SUN STORIES TOPICS TO TANGENT SPHERE TO BODY
STORIES ROUTE WITH LIFE NOTES
THE TOPIC OF CLOSED OFF TUBE ROUTE WITH STORIES OF DIRECTIONAL STORIES ROUTE WITH LIFE NOTES
TO PERHAPS VALUE THAT VARIABLE OF STORIES UNDERWATER
TO WORK THIS DIGNITY AND EGO STORY ROUTE WITH LIFE
IN STORIES OF THAT TOPIC OF ISSUE WONDERS TO NOTE WORK WITH STORIES OF TUBE VALUE PATH WITH THE STORY
OF TOPIC OF THE SIZEMIC ENERGY EFFECTED BY CRYOGENIC MACHINE OF EFFECT PATH OF NUCLEAR STORIES ROUTE WITH
STORIES IN TOPIC OF STORIES THAT PRESSURE EFFECT SPACE WORKING
ELECTRON WITH PROTON STORY OF PATH BASHING PROTONS ISSUE EFFECT WEATHER DOUBLES STORY WITH PATH NOTES
ROUTE OF TOPIC TO WORK THAT STORY ROUTE WITH PATH OF NOTES IN NOT DO BASHING PROTONS ROUTE WITH NOTES
HOWEVER ADD ELECTRON AND WORK WITH TOPICS NOTES STORIES NOTE ROUTE WITH THAT PATH OF ROUTE NOTES
NOTE ISSUE STORIES OF LIFE WITH ATTACKS DOUBLE MIMIC AND STORIES OF PATH WITH WHITE LIGHT GAP STORIES
ISSUE CONCERNS ROUTE WITH NOTES STORIES
ALSO CONCERNS WITH STORIES TO PATH NOTE ROUTE OF ISSUE PATH PERHAPS WHY WE ARE IN BAKING SODA OPIATES
AND BAKING SODA COCA ROUTE WITH STORIES
TOPICS ALSO ROUTE WITH STORIES
OF ISSUE ROUTE TO NOTES STORIES NOTES
STORIES OF ATTACK STORIES OF ROUTE TOPICS OF EXTRA PLANE IN LIFE STORIES TOPICS TO 911 SIMULATED GIANT BODY
ROUTE WITH PATH STORIES OF PATH STICKY PATH WITH ROUTE OF MEDS STORY NOTES TOPICS ALSO STORIES NOTES
TO STORIES ROUTE WITH NOTES
PAST TO NOTES — — — — — — — - XXXXXXXXXXXXXXXXXXXXXXX IMPROVE THE ISSUE OF RELATIONSHIP OF NOTE 5 ANTENNA VIBE TO NOTES SOUND IS A PATH OF PRESSURE TO LIGHT ACTUALLY VIBE TO NOTES MAKE THE METAL OUT OF THE HYDROGEN SULFIDE TO NOTES LIGHTENING WENT TO GREEN NOTES VIBE EVENT TO NOTES NOT EVEN DOWN THE ROD VIBE TO NOTES https://www.youtube.com/watch?v=td0WEtf1pQk XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX It was evident that calcium hydroxide increased recruitment, migration, proliferation, and mineralization of the DPSCs and periodontal ligament stem cells. pubmed.ncbi.nlm.nih.gov/20055661/ Dental stem cell therapy with calcium hydroxide in dental … HYDROXIDE EFFECT ON STEM CELLS
TOPIC OF MOOD MAKES US DIFFERENT TO HISTORY METHODIC TREE CLIMB TAKEN ROUTE WITH STORIES OF LIFE WITH ISSUE A TOPIC OF FLURRY BODY OF ROUTE 2 DIRECTION AND ANY DIRECTION STORIES ROUTE WITH ISSUE TO RELATE TO CHOICE OF DIRECTION STORY OF TOPIC ISSUE
STORY OF FLURRY ROUTE WITH 2 DIRECTION OF BODY DREAM ROUTE WITH LIFE STORIES TO ANY DIRECTION AND STORIES
OF PERSPECT SELF TO ANY DIRECTION AND STORY OF ISSUE THAT STORY IN FLURRY TO BODY ROUTE WITH ALSO
100 000 YEARS DREAMS OF STORY OF POLE TO TUBE STORY ROUTE WITH PATH TOPICS OF ISSUE TO NOTE BIKE PUMP STORIES
ROUTE WITH TRIANGLE 3D SHAPE ROUTE PREFIX SUFFIX ISSUES OF DREAM OF STORIES OF TOPIC PATH NOTES OF THAT STORY ROUTE WITH NOTES
STORY OF ISSUE ROUTE TO NOTES
MANY EVENT OF UPRIGHT METAL ATTACKS STORY HISTORY AND MEMORY BODY STORIES ARE 2 GENERAL ISSUE ON THE ATTACK SIDE STORIES
OF A NUMBER ISSUE TOPIC BOTHER GETTING INTO NUMBER TOPIC CONCERNS NOW STORIES WORKING THROUGH THIS TARGET
STORY NOTES ISSUE OF 2 ISSUE NOTES STORIES NOTES ALSO NOTES
FLOW OF SOLVENTS IN LIFE PRICE OF TOOL IN LIFE STORY OF VALUE OF LIFE TO STORY OF ISSUE TO NOTES PATH OF A MED IN LIFE
ISSUE IN LIFE TO STORY WONDERS ADD COIL TO SOLAR POWER IN LIFE STORY WITH ROUTE REJUVINATE MURITIC ACID VIBE
STORY AND RUN THE STORY OF SULFITES OF MEDS BACKWARDS THEN BULK AND THEN DRIP STORY VIBE TO NOTE ISSUES
ISSUE VIBE TO SULFIDE TO FLORIDE IONIC PATH TO NOTE DIRT WITH BACKWARS MURITIC ACID VIBE STORY WITH TO NOTE THEN TO DIETHYL ETHER
Oct 1, 2018 · Attempts to selectively oxidize mustard gas [(ClCH 2 CH 2) 2 S, abbreviated as BCES] to the non-toxic sulfoxide using a trans-Ru(TMP)(O) 2 /O 2 catalyst (TMP = porphyrin dianion of 5,10,15,20-tetramesitylporphyrin) have led to isolation and characterization, including an X-ray structure, of trans-Ru(TMP)(BCES) 2, the first such report of a ...
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During our studies on the oxidation of thioethers to sulfoxides [1], [2], [4], we were contacted by the Canadian Department of Defence, and received contract grants to investigate whether such chemistry was applicable to ‘Mustard Gas’ [bis(β-chloroethyl) sulfide, abbreviated as BCES]; this is a treacle-like liquid, whose vapour is toxic. The key factor is that the sulfoxide (ClCH2CH2)2SO is crystalline and as such is essentially non-toxic, while further oxidation generates the vesicant toxic sulphone [8]. Our studies ended in 1993, and reviews and new studies on reactivity of BCES, the simulant 2-chloroethyl(ethyl)sulfide (CEES), and other models, continue to appear [9], [10]; metal-organic framework systems are becoming increasingly involved [10](a), [10](b), and include studies on catalyzed selective oxidations to the sulfoxides [10b].
The thioethers Et2S and CEES, thiodiglycol, SOCl2, acetone, acetonitrile, and other common chemicals (all Aldrich products), and the deuterated solvents acetone-d6 and C6D6 (from MSD Isotopes), were used as received. The Ru source was obtained on loan from Johnson, Matthey Ltd. as RuCl3·3H2O (∼40% Ru), and the H2(TMP) and H2(OCP) porphyrins were kindly provided by D. Dolphin of this department.
1H and 13C{H} NMR spectra were measured on a Varian XL-300 or a Bruker AC200F spectrometer, with
Results and discussion
BCES (Mustard) was synthesized in small amounts by the reaction shown in Eq. (1), and is of high purity based on 1H and 13C{1H} NMR data. Only one previous publication in 1988 has reported 1H data, the δ values being given as 3.68 (Cl-CH2) and 2.92 (CH2-S) for the neat compound in the absence of solvent [17]: the multiplicities were not noted but our triplets measured in acetone-d6 (Table 1) are in excellent agreement and, as expected, are significantly downfield (∼2.5 ppm) from the CH3 triplet